If you instead make a chart from multiple rows and multiple columns, Excel will make one dimension the x-axis and make the other into different series.

This article explains how to add a secondary axis to a chart in Excel so you can view unlike categories on the same graph. These instructions work in Excel in Microsoft 365, Excel 2021, Excel 2019 ...

Naming Basics Best practice recommendations are to create a chart placing independent variables on the horizontal, x-axis and dependent variables on the vertical, y-axis.